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High-Temperature Hot Air/Silane Coupling Modification of Wood Fiber and Its Effect on Properties of Wood Fiber/HDPE Composites.

Identifieur interne : 001357 ( Main/Exploration ); précédent : 001356; suivant : 001358

High-Temperature Hot Air/Silane Coupling Modification of Wood Fiber and Its Effect on Properties of Wood Fiber/HDPE Composites.

Auteurs : Feng Chen [République populaire de Chine] ; Guangping Han [République populaire de Chine] ; Qingde Li [République populaire de Chine] ; Xun Gao [République populaire de Chine] ; Wanli Cheng [République populaire de Chine]

Source :

RBID : pubmed:28772646

Abstract

The surfaces of poplar wood fibers were modified using high-temperature hot air (HTHA) treatment and silane coupling agent. The single factor test was then used to investigate the performances (e.g., the change of functional groups, polarity, cellulose crystallinity, and thermal stability) of modified poplar wood fibers (mPWF) through Fourier transform infrared spectrometry, X-ray diffraction and thermo-gravimetric analysis for the subsequent preparation of wood-plastic composites (WPCs). The effect of HTHA treatment conditions-such as temperature, inlet air velocity, and feed rate-on the performances of WPCs was also investigated by scanning electron microscopy and dynamic mechanical analysis. The main findings indicated that HTHA treatment could promote the hydration of mPWF and improve the mechanical properties of WPCs. Treatment temperature strongly affected the mechanical properties and moisture adsorption characteristics of the prepared composites. With the increase of treated temperature and feed rate, the number of hydroxyl groups, holocellulose content, and the pH of mPWF decreased. The degree of crystallinity and thermal stability and the storage modulus of the prepared composites of mPWF increased. However, dimensional stability and water absorption of WPCs significantly reduced. The best mechanical properties enhancement was observed with treatment temperature at 220 °C. This study demonstrated the feasibility for the application of an HTHA treatment in the WPC production industry.

DOI: 10.3390/ma10030286
PubMed: 28772646
PubMed Central: PMC5503328


Affiliations:


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